Dichlorido{2-morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ3 N,N′,N′′}zinc(II)
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چکیده
In the title compound, [ZnCl(2)(C(13)H(19)N(3)O)], the Schiff base ligand acts as an N,N',N''-tridentate chelating agent, making two five-membered rings with the Zn(II) ion. The metal atom is five-coordinated by the Schiff base ligand and two Cl atoms in a distorted square-pyramidal geometry. An intra-molecular C-H⋯Cl inter-action occurs. In the crystal, adjacent mol-ecules are linked together via C-H⋯Cl hydrogen-bonding and long range C-H⋯O and C-H⋯Cl inter-actions into a three-dimensional network.
منابع مشابه
Dibromido{2-morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ3 N,N′,N′′}zinc(II)
In the title complex, [ZnBr(2)(C(13)H(19)N(3)O)], the Zn(II) atom is five-coordinated by the three N-donor atoms of the Schiff base ligand and by two Br atoms in a distorted square-pyramidal geometry. The morpholine ring adopts a chair conformation.
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